Lexikon

chemical weathering is caused by rain water reacting with the mineral grains in rocks to form new minerals (clays) and soluble salts. These reactions occur particularly when the water is slightly acidic.

These chemical processes need water, and occur more rapidly at higher temperature, so warm, damp climates are best.It means that soil formation is faster under tropic klimate compared to moderate or cold climate.

Chemical weathering (especially hydrolysis and oxidation) is the first stage in the production of soils.
There are different types of chemical weathering, the most important are:

Solution - removal of rock in solution by acidic rainwater. In particular, limestone is weathered by rainwater containing dissolved CO₂, (this process is sometimes called carbonation).

Hydrolysis - the breakdown of rock by acidic water to produce clay and soluble salts.

Oxidation - the breakdown of rock by oxygen and water, often giving iron-rich rocks a rusty-coloured weathered surface.