Lexikon

1951 - 2000 / 2263 megjelenítése
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stagnant water
standard aquatic microcosm
Standardized Aquatic Microcosm (SAM)
type of microcosm for laboratory testing of water-ecosystem.
starter culture

a starter culture is a microbiological culture which actually performs a biotechnological process (fermentation). These starters usually consist of a cultivation medium, colonized by the microorganisms used in the biotechnology.

stationary phase

in chromatography, the porous solid or liquid phase through which an introduced sample passes. The different affinities the stationary phase has for a sample allow the components in the sample to be separated or resolved.

statistical evaluation of toxicity test-results
statistics

a branch of mathematics that deals with collecting, reviewing, summarizing, and interpreting data or information. Statistics are used to determine whether differences between study groups are meaningful.

steady noise

unceasing prolonged noise, without interruption.

steady noise, constant noise

unceasing prolonged noise, without interruption. It is a constant noise, when the deviation in the decibel is not more than 5 dB.

steam heating of soil

steam heating of the soil is one specific method where soil or solid wastes are heated by means of stream and is a category within the umbrella term of “thermally enhanced recovery”. It mens the enhanced recovery of volatile or volatilized contaminants from contaminated soil. I can be applied ex situ or in situ.

step sound insulation
stir-bar sorptive extraction
a new solventless sample preparation method for the extraction and enrichment of organic compounds from aqueous matrices. The method called also as Twister technique is based on the same principles as solid-phase microextraction (SPME). Compared with SPME, a relatively large amount of extracting phase (SPME 0.5 microliters; Twister 50 microliters) is coated on a stir bar. Solutes are extracted into the coating poly(dimethyl siloxane, PDMS) of a stir-bar, based upon their octanol-water partitioning coefficient. In contrast to SPME, in which desorption is performed in the inlet of a gas chromatograph, stir-bar sorptive extraction is used in combination with a thermal-desorption system. After desorption the stir-bar can be used again. The technique has been applied successfully to trace analysis in environmental, biomedical and food applications, e.g. for determination of trace hydrocarbons, PAHs, PCBs in water. Users can obtain extremely low detection limits with good reproducibility. (Source: F. David, B. Tienpont and P. Sandra: Stir-Bar Sorptive Extraction of Trace Organic Compounds from Aqueous Matrices, LCGC Europe, 2003, 1-7)
stndardisation of ecotoxicity testing
stove
STP

Sewage Treatment Plant

Strategic Approach to International Chemicals Management (SAICM)

Strategic Approach to International Chemical Management (SAICM) adopted on 6 February 2006 in Dubai.

SAICM supports the achievement of the goal agreed at the 2002 Johannesburg World Summit on Sustainable Development of ensuring that, by the year 2020, chemicals are produced and used in ways that minimize significant adverse impacts on the environment and human health.

Source: http://www.saicm.org/index.php?ql=h&content=home

Streckeisen system diagram

a Streckeinsen or QAPF diagram is a double triangle diagram used to classify igneous rock based on mineralogic composition. The diagram is based on the fundamental work of many petrologists which was fully summarised by Strekeisen in 1973 and 1976. The QAPF diagram was completed and recommended by the International Union of Geological Sciences, IUGS. Geologists use it worldwide as a classification of igneous, especially plutonic igneous rocks. The QAPF by acronym, stands for "Quartz, Alkali feldspar, Plagioclase, Feldspathoid (Foid)". The mineral groups used for classification of igneous rocks are the following: Q = Quartz, A = Alkali feldspar, P = Plagioclase, F = Feldspathoid (Foid), M = Mafic (silicate mineral rich in magnesium and iron). Groups Q, A, P, F comprise the felsic minerals. The sum of Q+A+P+F+M must be 100%. However there can never be more than four non-zero values, as the minerals in groups Q and F are mutually exclusive i.e. if Q is present F must be absent and viceversa. The classification is divided into two parts: If mafic minerals (M) are less than 90% (M<90) the rock is classified according to its felsic minerals in the QAPF double triangle diagram. The basic idea of classification is that minerals belonging to the Q and F mineral groups do not occur simultaneously as primary minerals in the same igneous rock, because the SiO2 surplus in the melt reacts with the Feldspathoids resulting feldspars. For this reason maximum three of the Q, A, P, F mineral groups may occur in an igneous rock type. If mafic minerals make up more than 90% of the rock composition (M≥90), it is an ultramafic rock and it is classified according to its mafic minerals. In this case two triangle diagrams are used (olivine–orthopiroxene–clinopyroxene, olivine–pyroxene–amphibole).

stripping
structural aberration

a change in chromosome structure detectable by microscopic examination of the metaphase stage of cell division, observed as deletions and fragments, intrachanges or interchanges. This fenomenon used in genotoxicity tests, where the experimental unit is the cell, and therefore the percentage of cells with structural chromosome aberration(s) should be evaluated. Different types of structural chromosome aberrationsshould be listed with their numbers and frequencies for experimental and control cultures.

structure-borne noise

sound that travels over at least part of its path by means of the vibration of a solid structure.

study summary
a summary of the objectives, methods, results and conclusions of a full study report providing sufficient information to make an assessment of the relevance of the study. (Source: REACH Glossary)
sub basin

the area of land from which all surface run-off flows through a series of streams, rivers and, possibly, lakes to a particular point in a water course (normally a lake or a river confluence).

substance identity data, REACH

The information required to identify a substance is defined in Annex VI, 2, of REACH, and is reproduced in the table below.

If it is not technically possible, or does not appear scientifically necessary to provide certain information, the reasons should be stated.

If you are involved in a joint registration, it is very important that you have agreed ‘sameness’ of your substances, and the information you each provide here should support this. There is no legal definition of "sameness" but any inconsistencies identified by ECHA or MSCAs that suggest your substances are significantly different could lead to requests for further information, or rejection of registration dossiers.

ECHA Technical Guidance: Guidance for identification and naming of substances under REACH 

Annex VI clauseInformation requirement
2.1Name or other identifier of the substance

2.1.1

IUPAC name or other international chemical name

2.1.2

Other names, e.g. trade name, abbreviation

2.1.3

EC Number

2.1.4

CAS name and CAS number

2.1.5

Other identity code
2.2Information related to molecular and structural Formula

2.2.1

Molecular and structural formula (including SMILES notation, if available)

2.2.2

Optical activity and typical ratio of (stereo) isomers ( if applicable and appropriate)

2.2.3

Molecular weight or molecular weight range
2.3Composition

2.3.1

Degree of purity

2.3.2

Nature of impurities, including isomers and by-products

2.3.3

Percentage of (significant) main impurities

2.3.4

Nature and order of magnitude (…ppm, …%) of any additives

2.3.5

Spectral data (UV,IR,NMR or mass spectrum)

2.3.6

High pressure liquid chromatogram, gas chromatogram.

2.3.7

Description of the analytical methods or the appropriate bibliographical references fro the identification of the substance and, where appropriate, for the identification of impurities and additives. This information shall be sufficient to allow the methods to be reproduced.

Source: http://www.reach-serv.com/index.php?option=com_content&task=view&id=160&Itemid=64

Substance Information Exchange Forum (SIEF)

A SIEF is a forum, formed after the pre-registration phase, to share data on a given phase-in substance.
The principal aims of a SIEF are to:
i) facilitate data sharing for the purposes of registration
ii) agree on the classification and labelling of the substance where there is a difference of interpretation between the potential registrants. Source: REACH Glossary.

Substance Information Exchange Forum (SIEF), REACH

data sharing is one of the core principles in the REACH Regulation. By submitting dossiers jointly and sharing information on substances, companies increase the efficiency of the registration system, reduce costs and avoid unnecessary testing on vertebrate animals.

A potential registrant can choose to request data which does not involve testing on vertebrate animals. However, the potential registrant must request data which involves testing on vertebrate animals.

Indeed, studies involving testing on vertebrate animals have to be shared in any case.

This means that new studies involving vertebrate animals can only be conducted if the data cannot be generated by any other means. This principle is valid for both phase-in and non- phase-in substances.

Source: http://echa.europa.eu/datasharing_en.asp

Substances of Very High Concern (SVHC), REACH
Substances of Very High Concern
Substances of Very High Concern = SVHC
substrate
subsurface permeable reactive barriers
subsurface water, and its contamination

sub-surface water, is fresh water located in the pore space of soil and rocks. It is also water that is flowing within aquifers below the water table. Sometimes it is useful to make a distinction between sub-surface water that is closely associated with surface water groundwater and deep sub-surface water in an aquifer sometimes called "fossil water".

Subsurface waters are generally polluted from the unsaturated soil layer beyond. Pipelines, underground containers, surface land-uses are the most frequent pollution sources. The contaminants in the subsurface waters may naturally attenuate due to dilution, chemical reactions or biodegradation. As the redoxpotential in the subsurface waters is relative low anoxic or anaerobic conditions, the biodegradation of pollutants is generally low, needs some enhancement by engineering/biotechnological tools to increase efficiency.

sugar flushing technology

remediation technology for contaminated soil and groundwater, an innovative version of pump and treat technology applying a sugar, a cyclodextrin (hydroxypropyl cyclodextrin) for the enhancement of the solubility of organic contaminants. It was developed in the USA and applied with success for remediation of military sites contaminated by e.g. trichloroethylene. Injecting the cyclodextrin solution into the injection wells, the ground water containing the contaminant in enhanced concentration is extracted from the extraction wells and treated by activated carbon or by distillation. The regenerated cyclodextrin solution is re-injected into the ground water. (see MOKKA database sheet No. 183) Further literature: Boving, T.B. and Brusseau, M.L. (2000) Solubilization and removal of residual trichloroethene from porous media: comparison of several solubilization agents. J. Contam. Hydrol., 42(1), 51-67; Boving, T.B., Barnett, S.M., Perez, G., Blanford, W.J. and McCray, J.E. (2007) remediation with cyclodextrin: recovery of the remedial agent by membrane filtration. Remed. J., 17, 21-36.

suitable passive acoustic protection
sulcotrione

Sulcotrione is a foliar herbicide. Its mode of action is the Inhibition of 4-hydroxyphenyl-pyruvate-dioxygenase (4-HPPD).

Common name (ISO): Sulcotrione
Chemical name (IUPAC): 2-(2-chloro-4-mesylbenzoyl)cyclohexane-1,3-dione
Chemical name (CA): 1,3-cyclohexanedione, 2-[2-chloro-4-(methylsulfonyl)-benzoyl]-
CIPAC No: 723; CAS No: 99105-77-8;
Minimum purity: 950 g/kg (on a dry weight basis)
Molecular formula:: C14 H13 Cl O5 S
Identity of relevant impurities (of toxicological, ecotoxicological and/or environmental concern)
Hydrogen cyanide: maximum content 80 mg/kg on a dry weight basis
Toluene: maximum content 4 g/kg on a dry weight basis.
Molecular mass: 328.77 g/mol

The Standing Committee of the EUROPEAN COMMISSION HEALTH AND CONSUMERS DIRECTORATE-GENERAL on the Food Chain and Animal Health at its meeting on 28 October 2008 decidedon the inclusion of sulcotrione in Annex I of Directive 91/414/EEC (the placing of plant protection products on the market).

The following reference values have been finalised as part of the re-evaluation:
ADI: 0.0004 mg/kg bw/day
ARfD: not allocated, not necessary
AOEL: 0.0006 mg/kg bw/day.

Complete characterisation:

General status:

Pesticide Type Herbicide
Chemical Group Triketone
Substance origin Synthetic
Mode of Action Absorbed mainly by the leaves but also some root uptake. 4-HPPD inhibitor.
CAS RN 99105-77-8
EC Number -
CIPAC Number 723
US EPA Chemical code -
Chemical Formula C14H13ClO5S
SMILES O=C(c1ccc(cc1Cl)S(=O)(=O)C)C2C(=O)CCCC2=O
International Chemical Identifier (InChI) InChI=1/C14H13ClO5S/c1-21(19,20)8-5-6-9(10(15)7-8)14(18)13-11(16)3-2-4-12(13)17/h5-7,13H,2-4H2,1H3
Structure diagram available? Yes
Molecular Mass (g mol-1) 328.77
IUPAC Name 2-(2-chloro-4-mesylbenzoyl)cyclohexane-1,3-dione
CAS Name 2-[2-chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione
Other status information -
Herbicide Resistance (HRAC) Classification F2
Insecticide Resistance (IRAC) Classification Not applicable
Fungicide Resistance (FRAC) Classification Not applicable
Physical State White solid

ENVIRONMENTAL FATE

Property Value Source/Quality Score/Other Information Interpretation
Solubility - In water at 20oC (mg l-1) 1670 A4 High
Solubility - In organic solvents at 20oC (mg l-1) 2000 A5 - Xylene -
190000 A5 - Dichloromethane -
48000 A5 - Acetone -
300 A5 - 1-Octanol -
Melting Point (oC) 139 A5 -
Boiling Point (oC) Decomposes before boiling A5 -
Degradation point (oC) 170 A5 -
Flashpoint (oC) Not highly flammable A5 -
Octanol-water partition coefficient at pH 7, 20oC P 2.00 X 10-02 Calculated -
Log P -1.7 A5 Low
Bulk density (g ml-1)/Specific gravity - - -
Dissociation constant (pKa) at 25oC 3.13 A5 -
Note: Weak acid
Vapour pressure at 25oC (mPa) 5.00 X 10-03 A5 Volatile
Henry's law constant at 25oC (Pa m3 mol-1) 6.0 X 10-07 A5 Non-volatile
Henry's law constant at 20oC (dimensionless) 4.33 X 10-09 Q2 Non-volatile
GUS leaching potential index 3.42 Calculated High leachability
SCI-GROW groundwater index (µg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Value 4.02 X 10-01 Calculated -
Note -
Potential for particle bound transport index - Calculated Low
Maximum UV-vis absorption
L mol-1 cm-1
285nm = 15239, 283.5nm = 16868, 259 nm = 20364 A5 -
Surface tension (mN m-1) 69.0 A5 at 20oC, 90% solution -

Degradation:

Property Value Source/Quality Score/Other Information Interpretation
Soil degradation (days) (aerobic) DT50 (typical) 25 A5 Non-persistent
DT50 (lab at 20oC) 25.3 A5 Non-persistent
DT50 (field) 3.6 A5 Non-persistent
DT90 (lab at 20oC) 100.2 A5 -
DT90 (field) 18.4 A5 -
Note EU dossier lab studies DT50 range 10.8-89.7 days, DT90 range 47-246 days; field studies DT50 range 1.2-11.4 days, DT90 range 6.9-38 days
Aqueous photolysis DT50 (days) at pH 7 Value 25.6 A5 Slow
Note pH sensitive: DT50 13 days at pH 4, 40.9 days at pH 9, all data for 5 cm depth and seasonal mean values. Degradation slower at 30 cm depth.
Aqueous hydrolysis DT50 (days) at 20oC and pH 7 Value Stable A5 Very persistent
Note Stable at pH 5 to pH 9, temp 25-40 Deg C
Water-Sediment DT50 (days) 63.9 A5 Moderately fast
Water phase only DT50 (days) 9.5 A5 Moderately fast

Soil adsorption and mobility:

Property Value Source/Quality Score/Other Information Interpretation
Linear Kd - - -
Koc -
Notes and range -
Freundlich Kf 1.05 A5 Mobile
Kfoc 36
1/n 0.839
Notes and range EU dossier Kf range 0.29-2.26, Kfoc range 17-58 mL/g, 1/n range 0.812-0.888, Soils=6
pH sensitivity Predominantly OC-dependent but pH-dependent to a minor extent

Key metabolites:

Metabolite Formation Medium Estimated Maximum Occurrence Fraction 91/414 Relevancy
2-chloro-4-methylsulfonyl-benzoic acid Soil 0.603 Major fraction, Relevant

Other known metabolites:

Metabolite name and reference Aliases Formation Medium / Rate Estimated Maximum Occurrence Fraction Metabolising Enzymes
4-hydroxyphenyl pyruvate - Rat (Blood) - -
4-hydroxy-sulcotrione, 2-[2-chloro-4-(methylsulfonyl)benzoyl]-4-hydroxycyclohexane-1,3-dione sulcotrione metabolite M02 Rat (Urinary) - -
5-hydroxy-sulcotrione, 2-[2-chloro-4-(methylsulfonyl)benzoyl]-5-hydroxycyclohexane-1,3-dione sulcotrione metabolite M04 Rat (Urinary) - -


ECOTOXICOLOGY

Property Value Source/Quality Score/Other Information Interpretation
Bio-concentration factor BCF - - -
CT50 (days) - -
Bioaccumulation potential - Calculated Low
Mammals - Acute oral LD50 (mg kg-1) > 5000 A5 Rat Low
Mammals - Short term dietary NOEL (mg kg-1) > 0.5 L2 Rat, 2 year High
(ppm diet) > 100 -
Birds - Acute LD50 (mg kg-1) > 1350 A5 Anas platyrhynchos Moderate
Birds - Short term dietary (LC50/LD50) > 1259 mg kg bw-1 day-1 A5 Anas platyrhynchos -
Fish - Acute 96 hour LC50 (mg l-1) 227 A5 Oncorhynchus mykiss Low
Fish - Chronic 21 day NOEC (mg l-1) 3.2 A4 Oncorhynchus mykiss, Juvenile growth -
Aquatic invertebrates - Acute 48 hour EC50 (mg l-1) > 848 A5 Daphnia magna Low
Aquatic invertebrates - Chronic 21 day NOEC (mg l-1) > 75 A5 Daphnia magna -
Aquatic crustaceans - Acute 96 hour LC50 (mg l-1) - - -
Sediment dwelling organisms - Acute 96 hour LC50 (mg l-1) - - -
Sediment dwelling organisms - Chronic 28 day NOEC, static, water (mg l-1) - - -
Sediment dwelling organisms - Chronic 28 day NOEC, sediment (mg kg-1) - - -
Aquatic plants - Acute 7 day EC50, biomass (mg l-1) 0.051 A5 Lemna gibba Moderate
Algae - Acute 72 hour EC50, growth (mg l-1) 1.2 A5 Raphidocelis subcapitata Moderate
Algae - Chronic 96 hour NOEC, growth (mg l-1) - - -
Honeybees - Acute 48 hour LD50 (µg bee-1) 50 A5 Oral Moderate
Earthworms - Acute 14 day LC50 (mg kg-1) > 1000 A5 Moderate
Earthworms - Chronic 14 day NOEC, reproduction (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50product ha
EC50product ha
NOECproduct ha
% Effect
- - -
Other arthropod (1) LR50 g ha-1 450 48 hour
A5 Aphidius rhopalosiphi, adult
Moderately harmful at 1 kg ha-1
% Effect - - -
Other arthropod (2) LR50 g ha-1 450 7 day
A5 Typhlodromus pyri
Moderately harmful at 1 kg ha-1
% Effect - - -
Soil micro-organisms Nitrogen mineralisation: No significant effect
Carbon mineralisation: No significant effect
A5
Dose: 4.5 kg/ha, 28 days
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


HUMAN HEALTH AND PROTECTION

General:

Property Value Source/Quality Score/Other Information Interpretation
Mammals - Acute oral LD50 (mg kg-1) > 5000 A5 Rat Low
Mammals - Dermal LD50 (mg kg-1 body weight) > 4000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 1.63 A5 Rat, 4hr (nose only) -
Other Mammal toxicity endpoints -   -
ADI - Acceptable Daily Intake (mg kg-1bw day-1) 0.0004 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1bw day-1) None allocated A5 -
AOEL - Acceptable Operator Exposure Level - Systemic (mg kg-1bw day-1) 0.0006 A5 Rat, SF=100 -
Dermal penetration studies (%) 0.1-0.5 A5 concentration dependant -
Dangerous Substances Directive 76/464 - - -
Exposure Limits - - -
Exposure Routes Public [No unacceptable risks to bystanders identified for intended use]
Occupational [No unacceptable risks to operators or other workers identified for intended use]
Examples of European MRLs (mg kg-1) Value Maize: 0.05
Note [A5 EU dossier proposals]
For the EU pesticides database click here
Drinking Water MAC (µg l-1) - - -

Health issues: skin sensitiser, potential kidney and liver toxicant, may cause eye damage

Handling issues:

Property Value Source/Quality Score/Other Information Interpretation
General <="" font="" border="0"> [Not explosive or oxidising]
EC Risk Classification <="" font="" border="0"> [Reproduction risk category 3: R63], [Xi - Irritant: R43]
EC Safety Classification <="" font="" border="0"> -
WHO Classification NL - Not listed
US EPA Classification (formulation) No consensus across products or no products available - -
UN Number -
Waste disposal & packaging <="" font="" border="0"> -

 

 

Sources:

http://sitem.herts.ac.uk/aeru/iupac/Reports/600.htm

http://ec.europa.eu/food/plant/protection/evaluation/existactive/list_sulcotrione.pdf

http://compendium.bayercropscience.com/BAYER/CropScience/CropCompendium/BCSCropComp.nsf/id/sulcotrione.htm#

 

sulphur dioxide
summary report, REACH
supercritical fluid extraction
an extraction method (SCFE) where the extraction fluid, usually CO2 is present at a pressure and temperature above its critical point.
supersound
supplyer, REACH
surface tension
intrinsic property of liquids caused by cohesion (the attraction of molecules to similar molecules). Since the molecules on the surface of the liquid are not surrounded by similar molecules on all sides, they are more attracted to their neighbours on the surface. It corresponds to the minimum work required to expand the surface by one unit area (J/m2, N/m). A physico-chemical parameter required by REACH. Surface tension is not used as a Classification and Labelling (C&L) (classification and labelling of chemicals) criterion, to define PBT properties, or as a specific property in the chemical risk assessment. It can be used to provide guidance as to whether a chemical would be considered a surfactant under EU Regulation 648/2004 (last modified by Regulation 907/2006 - Detergents). (http://www.prc.cnrs-gif.fr/reach/en/physicochemical_data.html) The study need only be conducted if based on structure, surface activity is expected or can be predicted; or surface activity is a desired property of the material. If the water solubility is below 1 mg/l at 20°C the test does not need to be conducted.
surface water
surface water damage
Surface water sediment
surface water status

"surface water status" is the general expression of the status of a body of surface water, determined by the poorer of its ecological status and its chemical status.

surface waters ecological status

"ecological status" is an expression of the quality of the structure and functioning of aquatic ecosystems associated with surface waters, classified in accordance with Annex V. of the Water Framework Directive (WFD), 60/2000/EC

surface waters good chemical status

"good surface water chemical status" means the chemical status required to meet the environmental objectives for surface waters established in Article 4(1)(a) of WFD (60/2000/EC) that is the chemical status achieved by a body of surface water in which concentrations of pollutants do not exceed the environmental quality standards established in Annex IX and under Article 16(7), and under other relevant Community legislation setting environmental quality standards at Community level.

surface waters good ecological potential

"good ecological potential" is the status of a heavily modified or an artificial body of water, so classified in accordance with the relevant provisions of Annex V. of Water Framework Directive (WFD), (60/2000/EC).

surface waters good ecological status

"good ecological status" is the status of a body of surface water, so classified in accordance with Annex V. of WFD (Water Framework Directive), 60/2000/EC

Surfactant Enhanced Aquifer Remediation (SEAR)

Surfactant Enhanced Aquifer Remediation (SEAR), in its most basic form, could thus be considered a chemical enhancement to pump and treat. A chemical solution is pumped across a contaminated zone by introduction at an injection point and removal from an extraction point. To cover the entire contaminated zone, a number of injection and extraction wells are used; the well configuration is determined by the subsurface distribution of NAPL and the hydrogeologic properties of the aquifer.

SEAR is a source zone remediation technology. SEAR removes the residual phase contamination from which the dissolved phase plume is derived. Free phase contamination is typically removed by conventional pumping before SEAR is employed. SEAR does not have an immediate effect on the dissolved phase plume concentrations and is not a dissolved phase plume remediation technology. Removal of the source does however cause an intermediate and long-term reduction in dissolved phase contaminant concentrations.

Surfactants are unique chemical agents that greatly enhance the solubility of organic contaminants in aqueous media. They are also able to reduce the interfacial tension (IFT - that force existing where two fluids meet that keeps them as separate fluids) between the aqueous and organic phases to mobilize the organic phase. To illustrate the two mechanisms, we can use the familiar examples of the cleaning action of household cleaning detergents, which contain surfactants as a common constituent. We have witnessed surfactant-induced solubilization in the oily solution resulting from soaking oily pots and pans in dish detergent; we have observed a reduction in IFT from oil droplets or a sheen of oil coming off the pan due to the presence of a detergent. A surfactant flood can be designed to remove contaminants either primarily by solubilization or primarily by mobilization. Surfactant mobilization can remove more DNAPL in less time; however, there is greater risk of uncontrolled downward movement of DNAPL, as DNAPL is being physically displaced by the surfactant solution. Thus, to conduct a mobilization flood, it is necessary to have an aquitard as a barrier to prevent vertical DNAPL migration. It is important to identify from the outset whether solubilization or mobilization of DNAPL is desired, because not all surfactants can be used to conduct a mobilization flood.

The primary objective in SEAR design is to remove the maximum amount of contaminant with a minimum amount of chemicals and in minimal time while maintaining hydraulic control over the injected chemicals and contaminant. Each step in the design process must keep this in mind. Design challenges include precisely locating the DNAPL, finding the optimum surfactant solution for a given DNAPL composition and soil type, and fully characterizing the hydraulic properties of the aquifer, particularly the heterogeneities typically present in the subsurface environment. Because it is impossible to know with certainty the variations in aquifer properties over the treatment zone, numerical modeling tools are used to simulate how the system may respond in the presence of these unknown factors. Numerical modeling is also necessary to understand the dynamics of the flooding process under the hydrogeologic conditions at the site. SEAR has been acknowledged to be a promising, innovative technology for the removal of DNAPLs primarily because of the history of the use of surfactant-enhanced oil recovery by the petroleum industry.

Source: http://www.cpge.utexas.edu/ee/sear.html

survey

a systematic collection of information or data. A survey can be conducted to collect information from a group of people or from the environment. Surveys of a group of people can be conducted by telephone, by mail, or in person. Some surveys are done by interviewing a group of special people.

Environmental survey is data collection about an area, a catchment, about ecosystems and ecosystem members, about contamination at a site or the integrated collection of many different information.

suspendible part of the soil